Mg-Ni-Y储氢合金规模化制备及薄片与压制块体的储氢性能和循环稳定性研究Scalable Preparation of Mg-Ni-Y Hydrogen Storage Alloys: Hydrogen Storage Performance and Cycling Stability of Sheets and Pressed Compacts
郭嘉成,杨欣宇,唐伟能
摘要(Abstract):
镁基储氢材料因其高储氢容量、资源丰富、成本低成为氢能存储核心候选材料,但其规模化生产中的成分偏析、加工难及安全性问题制约产业化。本文针对Mg-Ni-Y合金,开发“规模化熔炼-精密切削-冷压成型”一体化工艺,探究了制备工艺对材料结构与储氢性能的影响规律。200 kg级熔炼制备的铸锭成分偏差≤0.5%,氮气保护下精密切削成0.1, 0.2和0.5 mm薄片,再冷压成块体。350℃吸放氢测试结果显示:0.1 mm薄片储氢密度为5.7%,接近同等成分~180μm粉末的6.0%,且规避粉末氧化、运输安全风险,兼具可卷绕、易压制成型的优势;压制块体初始储氢密度5.4%, 100次循环后仍存5.13%(衰减率为5%)。本文突破Mg-Ni-Y材料“高性能与规模化生产”协同瓶颈,制备的薄片与块体兼具优异储氢性能和稳定量产能力,推动镁基储氢材料工程化应用。
关键词(KeyWords): Mg-Ni-Y储氢合金;储氢性能;薄片;块体
基金项目(Foundation): 国家重点研发计划项目(2023YFB3809102);; 宝武集团重点研发项目(R25BGJS010-J)资助
作者(Author): 郭嘉成,杨欣宇,唐伟能
DOI: 10.13373/j.cnki.cjrm.XY25080013
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