尹成杰,贾锐,胡劲松

• 1:安徽理工大学化工与爆破学院
• 2:安徽理工大学安徽省煤炭资源综合利用工程技术研究中心

摘要(Abstract)：

水系锌离子电池（AZIBs）因其高安全性、低成本和环境友好特性成为下一代储能技术的研究热点。然而，其正极材料在循环稳定性、容量和倍率性能方面仍面临挑战。本文系统综述了稀土元素（如镧（La）、铈（Ce）和钇（Y）等）与高价值过渡金属（如银（Ag）、钼（Mo）和钌（Ru）等）掺杂对MnO_2, V_2O_5等正极材料的结构与性能调控机制。稀土元素通过扩大层间距、引入氧空位、增强结构稳定性，显著提升Zn~(2+)扩散动力学与循环寿命；高价值过渡金属则通过提升导电性、促进H~+/Zn~(2+)协同存储、抑制材料溶解，实现高容量与高倍率性能。本文总结了掺杂策略的关键机制，分析了当前面临的挑战，并展望了未来在AZIBs正极材料设计中的发展方向。

关键词(KeyWords)： 水系锌离子电池(AZIBs);正极材料;稀土金属;高价值过渡金属

Abstract:

Keywords:

基金项目(Foundation): 安徽高校自然科学研究项目（2024AH050395）资助

作者(Author): 尹成杰,贾锐,胡劲松

DOI: 10.13373/j.cnki.cjrm.XY25070004

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